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排序方式: 共有957条查询结果,搜索用时 89 毫秒
931.
Jun Xing Zu Peng Chen Fang Yuan Xiao Xue Yan Ma Ci Zhang Wen Dr. Zhen Li Prof. Hua Gui Yang 《化学:亚洲杂志》2013,8(6):1265-1270
Multicomponent Cu? Cu2O? TiO2 nanojunction systems were successfully synthesized by a mild chemical process, and their structure and composition were thoroughly analyzed by X‐ray diffraction, transmission electron microscopy, field‐emission scanning electron microscopy, and X‐ray photoelectron spectroscopy. The as‐prepared Cu? Cu2O? TiO2 (3 and 9 h) nanojunctions demonstrated higher photocatalytic activities under UV/Vis light irradiation in the process of the degradation of organic compounds than those of the Cu? Cu2O, Cu? TiO2, and Cu2O? TiO2 starting materials. Moreover, time‐resolved photoluminescence spectra demonstrated that the quenching times of electrons and holes in Cu? Cu2O? TiO2 (3 h) is higher than that of Cu? Cu2O? TiO2 (9 h); this leads to a better photocatalytic performance of Cu? Cu2O? TiO2 (3 h). The improvement in photodegradation activity and electron–hole separation of Cu? Cu2O? TiO2 (3 h) can be ascribed to the rational coupling of components and dimensional control. Meanwhile, an unusual electron–hole transmission pathway for photocatalytic reactions over Cu? Cu2O? TiO2 nanojunctions was also identified. 相似文献
932.
933.
934.
以XRD和IR为表征手段 ,以恒pH法为溶解实验方法 ,研究了 37℃下以铈单独处理和氟铈联用处理对二水磷酸氢钙 (CaHPO4 ·2H2 O ,DCPD)的水化产物及其溶解性质的影响。Ce3 不能促进DCPD向磷灰石转化 ,氟铈联用可加快DCPD的转化。随着Ce3 浓度的提高 ,DCPD经含Ce溶液单独处理后的产物主要为CaHPO4 (DCPA) Ce(PO4 )和Ce(PO4 )。DCPD经氟铈联用处理后的产物主要为DCPA (Ca2 ,Ce3 ) 1 0 -x(PO4 ) 6 -yF2 (F Ce HAP) Ce(PO4 )和F Ce HAP Ce(PO4 )。经 1?Cl3溶液单独处理后的DCPD的抗酸能力已有显著提高。氟铈联用促进溶解度更低的F Ce HAP的形成 ,因此效果优于铈单独处理 ,有可能成为一种有效的防龋方法。 相似文献
935.
Chloromethylated crosslinked co‐polyvinylbenzene‐divinylbenzene (2% DVB) was treated with triphenylphosphine and then with sodium bromate and hydrobromic add to afford red colored insoluble polyvinylbenzyltriphenylphosphonium supported tribromide. This reagent could be used as a mild and efficient monobrominating reagent for activated aromatic compounds such as phenols, aromatic ethers, aromatic amines and acetylanilines with good yields and high para‐selectivity. 相似文献
936.
Qing MU * Rong Wei TENG Chao Ming LI De Zu WANG Yu WU Han Dong SUN Chang Qi HU Phytochemistry Laboratory Kunming Institute of Botany Chinese Acadmy of Sciences Kunming School of Pharmacy Fudan University Shanghai 《中国化学快报》2001,(7)
Ongoing phytochemical studies on Goniothalamus species have led to the isolation of a number of annonaceous acetogenins and unusual new styryllactones which were found to possess significant cytotoxic activities against several hunan tumour cell lines1,2. Firstly, cyclopeptides were reported to be isolated from genus Goniothalamus in this paper.Goniothalamus leiocarpus is an evergreen tree which grows in the south of Yunnan, China. Four new anticancer styryllactones3,4 from the stem bark and… 相似文献
937.
原子吸收光谱法测定电解金属锰中微量金属杂质元素 总被引:3,自引:0,他引:3
本文用盐酸溶解样品,火焰原子吸收光谱法测定电解金属锰中K,Na,Ca,Mg,Fe,石墨炉原子吸收光谱法测定其中的Cr,Cu,Co,Ni含量。对测定条件进行了实验,找出最佳溶样方法和酸度,对共存元素的干扰有排除亦进行了试验,获得了满意的效果。该法简便、快速、准确,加标回收率为88.9%-108.7%之间,相对标准偏差为0.6%-6.7%,标准曲线法、标准加入法结果与对照结果相吻合,适用于电解金属锰样品金属杂质元素的分析。 相似文献
938.
Dr. Young J. Hong Sandra Irmisch Dr. Selina C. Wang Dr. Stefan Garms Prof. Jonathan Gershenzon Prof. Liansuo Zu Dr. Tobias G. Köllner Prof. Dean J. Tantillo 《Chemistry (Weinheim an der Bergstrasse, Germany)》2013,19(40):13590-13600
Terpene synthases, as key enzymes of terpene biosynthesis, have garnered the attention of chemists and biologists for many years. Their carbocationic reaction mechanisms are responsible for the huge variety of terpene structures in nature. These mechanisms are amenable to study by using classical biochemical approaches as well as computational analysis, and in this study we combine quantum‐chemical calculations and deuterium‐labeling experiments to elucidate the reaction mechanism of a triquinane forming sesquiterpene synthase from chamomile. Our results suggest that the reaction from farnesyl diphosphate to triquinanes proceeds through caryophyllyl and presilphiperfolanyl cations and involves the protonation of a stable (?)‐(E)‐β‐caryophyllene intermediate. A tyrosine residue was identified that appears to be involved in the proton‐transfer process. 相似文献
939.
A novel poly (ethylene glycol) bridged primary amine functionalized dicationic ionic liquid ([PA‐PEG1000‐DIL][BF4]) was synthesized and characterized by 1H‐NMR, 13C‐NMR, FT‐IR and ESI‐MS. The thermal gravimetric analysis (TGA) and differential scanning calorimetry (DSC) analysis indicated the high thermal stability of [PA‐PEG1000‐DIL][BF4]. It was used as an efficient and recyclable catalyst for the synthesis of substituted tetrahydrobenzo[b]pyrans through a one‐pot three‐component condensation of aromatic aldehydes, malononitrile and dimedone in 86% ~ 96% yields within 10 ~ 30 min in water. This method offers several advantages such as mild reaction conditions, simple operation and environmental friendliness. Furthermore, the catalyst could be easily recovered and reused for at least five runs without obvious loss of catalytic activity. 相似文献
940.
A numerical investigation of electrohydrodynamic (EHD) effects on bubble deformation under pseudo-nucleate boiling conditions 总被引:1,自引:0,他引:1
In this article, the electrohydrodynamic (EHD) effects on nucleate boiling are studied by developing a numerical modelling of EHD effect on bubble deformation in pseudo-nucleate boiling conditions. The volume of fluid (VOF) method is employed to track the interface between the gas–liquid two phases; the user-defined code is written and added to the commercial software FLUENT to solve the electric field and the corresponding electric body force. On this basis, the model is applied to study the EHD effects on heat transfer and fluid flows. An initial air bubble surrounded by liquid CCl4 and attached to a horizontal superheated wall under the action of electric field is studied. The results of the EHD effect on bubble shape evolution are compared with those of available experiments showing good agreement. The mechanism of EHD enhancement of heat transfer and the EHD induced phenomena including bubble elongation and detachment are analyzed in detail. 相似文献